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Q.

The enthalpy of neutralisation of HCl with NaOH is 57.3 kJ eq-1. If 0.6 moles of NaOH is mixed with 0.2 moles of HCl, the amount of heat liberated is

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a

9.5 kJ

b

11.46  kJ

c

20.93 kJ

d

19.03 kJ

answer is B.

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Detailed Solution

57.3 kJ is the heat liberated when I mol of HCl is neturalised by 1 mole of NaOH producing one mole of H2O
 for the neutralisation of 
0.2 NaOH + 0.2 HCl = 0.2 NaCl + 0.2H2O
the heat liberated = 0.2x57.3=11.46kJ

HCl is limiting reagent

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