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Q.

The enthalpy of neutralization of a strong monobasic acid by a strong monoacidic base is -13700 cal. A certain monobasic weak acid is  α pecrcent ionized in a molar solution. If the enthalpy of ionization of the weak acid is 5000 cal/mole and the enthalpy of neutralization of one molar solution of the weak acid is -9700 cal, then  α=

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Detailed Solution

ΔHstrongacid=13700 ΔHweakacid=9700 ΔHionisation=9700(13700) =4000 cal 1mole5000cal ?4000cal

Moles to be dissociated   =40005000= 0.8 mole
Degree of dissociation = 1-0.8 = 0.2

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