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The enthalpy of neutralization of a weak mono basic acid in 1M solution with a strong base is $-$ 56.1 kJ/mole. If enthalpy of ionization of the acid is 1.6 kJ/mole and enthalpy of neutralization of the strong acid with strong base is $-$ 57.3 kJ/mole. What is the % ionization of the weak mono basic acid in molar solution is----------------------

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Detailed Solution

$∆ H_{ionization} = ∆ H_{neutralization} - ∆ H_{(H^{+} + {OH}^{-} \to H_{2} O)} = - 56.1 - (- 57.3) = 1.2$

If no self ionization of weak mono basic acid occurs the $∆$ H_ionization= 1.6 kJ/mole

% ionization $= \frac{1.6 - 1.2}{1.6} \times 100$

=25

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