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Q.

The enthalpy of neutralization of a weak monoprotic acid (HA) in 1M solution with a strong base is -55.95 kJ/mol. If the unionized acid required 1.4 kJ/mol  heat for it's complete ionization and enthalpy of neutralization of the strong monobasic acid with a strong monoacidic base is -57.3 kJ/mol. What is the % ionization of the weak acid in molar solution?

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a

35.7%

b

3.57%

c

10%

d

1%

answer is B.

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Detailed Solution

The difference in energy in kJ/ mol is 

Step 1 

57.355.95=1.35kJ/mol

Percentage of ionization is found as,

Step 2

0.051.4×100=3.57% ionisation 

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