Q.

The enthalpy of neutralization of  NH4OH and CH3COOH is 10.5Kcalmol1 and enthalpy of neutralization of  CH3COOH with strong base is  12.5​ Kcalmol1  The enthalpy of ionization of  NH4OH will be

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a

4Kcalmol1

b

3Kcalmol1

c

2Kcalmol1

d

3.2Kcalmol1

answer is C.

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Detailed Solution

The enthalpy of ionization of  NH4OH (weak base) = enthalpy of neutralization of  NH4OH and CH3COOH - enthalpy of neutralization of  CH3COOH and strong base =  10.5(12.5) 

=10.5+12.5=2Kcalmol1

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