Q.

The enthalpy of solution at infinite dilution of hydrogen chloride gas in water is -74.85 kJ / mol. What is the heat with drawn when15 moles of water are added to the solution that contains 1 mole of hydrogen chloride gas dissolved in 25 moles of water, therefore temperature of the new mixture remains same?

HCl(g) + 25 aq.  HCl.25 aq.   ΔH= –72.03 kJ/mol
HCl(g) + 10 aq. HCl.10 aq.  ΔH= –69.01 kJ/mol
HCl(g) + 40 aq. HCl.40 aq.  ΔH= –72.79 kJ/mol

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a

2820 J/mol

b

3.02 kJ/mol

c

72.79 kJ/mol

d

760 J/mol

answer is A.

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Detailed Solution

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NCERT XI part-1 Page No 181.

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