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Q.

The equation which is balanced and represents the correct product(s) is

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a

Li2O+2KCl2LiCl+K2O

b

CuSO4+4KCNK2CuCN4+K2SO4

c

MgH2O62++EDTA4excess NaOHMgEDTA2++6H2O

d

CoClNH35+5H+Co2++5NH4++Cl

answer is B.

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Detailed Solution

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(a) Li2O+2KCl2LiCl+K2O

The above equation is incorrect because amine a stronger base cannot be generated by a weaker base, Li2O

(b) CoClNH35++5H+Co2++5NH4++Cl

The above equation is correct because amine complexes decompose under acidic medium. Thus, the complex [CoCl(NH3)5] decomposes under acidic conditions to give ammonium ions.

(c) MgH2O62++EDTA4excess NaOHMgEDTA2++6H2O

The above equation is incorrect because the product formed would be [Mg (EDTA)]2-.

(d) CuSO4+4KCNK2CuCN4+K2SO4

The above equation is incorrect. Thus, the correct equation is

2KCN+CuSO4K2SO4+Cu+CN2Cyanogen gas

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