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Q.

The equilibrium : 

 2CuICu0+CuII

in an aqueous medium, at 25° C shifts towards the left in the presence of :

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a

NO3

b

Cl

c

SCN

d

CN

answer is B, C, D.

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Detailed Solution

Cu2+ combines with CN- and SCN- ions to generate Cu(CN)43  and  Cu(SCN)43, respectively. Here, the complete reactions are given as,

Cu2++2CNCu(CN)22Cu(CN)22CuCN+(CN)2CuCN+3CNCu(CN)43Cu2++4SCNCu(SCN)42

Additionally, Cu2+ and  CuCl2 mix, and CuCl, which interacts with Cu to generate Cu, pushes the reaction in the other direction.

CuCl2+Cu2CuCl

Thus, the options b, c, and d are correct.

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