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Q.

The equilibrium concentrations in terms of mole are given for the reaction at 18 atm P mole at equation 

PCl53PCl33+Cl23 The value of Kp is ........

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answer is 6.

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Detailed Solution

Total pressure P=18atm.
The number of moles of PCl5​,PCl3 and Cl2​ are 3, 3 and 3 respectively.
The mole fractions of PCl5​,PCl3​ and Cl2  are 0.333, 0.333 and 0.333 respectively. 

The partial pressures of PCl5​,PCl3​ and Cl2​ are 0.333×18=6 atm,6 atm and 6 atm respectively.

Hence, the value of Kp is   Kp​=ppcl3×pcl2ppcl5=6×66 = 6

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