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Q.

The equilibrium constant for the ionization of R-NH2 (g) in water as :

RNH2(g)+H2O(l)RNH3+(aq)+OH(aq)

is 10- 6 at 25° C. Select correct statement(s).

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a

pH of solution is 11 and PRNH2(g)=1 1 bar

b

 Forward reaction is favoured by addition of RNH2 (g)

c

Forward reaction is favoured by addition of H2O(l)

d

Forward reaction is favoured by addition of HCI(aq)

answer is A, B, C, D.

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Detailed Solution

Given reaction is,

RNH2(g)+H2O(l)RNH3+(aq)+OH(aq)

Here,

Kb=106pOH=12pKblog c

 c=1 (active mass) 

Here, forward reaction is favoured by addition of HCI(aq),  H2O(l) or  RNH2 (g).

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The equilibrium constant for the ionization of R-NH2 (g) in water as :R−NH2(g)+H2O(l)⇌R−NH3+(aq)+OH−(aq)is 10- 6 at 25° C. Select correct statement(s).