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Q.

The equilibrium constant for this reaction is approximately 10-3.

HPO4-2aq.+HCO3-aq. H2PO4-aq.+CO3-2aq.

Which is the strongest  conjugate base in this reaction? 

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a

CO3-2aq.

b

HPO4-2aq.

 

c

 

HCO3-aq.

d

H2PO4-aq.

answer is D.

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Detailed Solution

Conjugate base of weak acid is strong base.

Keq=H2PO4-CO3-2HPO4-2HCO3-=10-3 HPO4-2W.Base+HCO3-W.AcidH2PO4-S.Acid+CO3-2S.Base  Since the Keq is very less, equilibrium lies on the L.H.S Equilibrium always moves from strong acid to weak acid. Thus H2PO4- is the strong acid and CO3-2 is the strong base.

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