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Q.

The equilibrium constant for 2H2S(g)2H2(g)+S2(g) is 0.0118 at 1300 K while the heat of dissociation is 597.4 kJ. The standard equilibrium constant of the action at 1200 K is :

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a

 1.180 X 10-4

b

11.80

c

118.0

d

cannot be calculated from given data

answer is A.

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Detailed Solution

logK1K2=ΔH2.303R1T11T2

logK10.0118=597.4×1032.303×8.3141120011300

K1=1.18×104

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