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Q.

The equilibrium constant (Kc) for the reaction  N2g+O2g 2NOg at temperature T is 4 × 10-4. The value of Kc, for the reaction, NOg 2NOg at temperature T is 4 × 10-4. The value of Kc,for the reaction, NOg 1/2N2g+1/2O2g at the same temperature is

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a

0.02

b

2.5 × 102

c

4 × 10-4

d

50.0

answer is D.

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Detailed Solution

We have

N2g+O2g 2NOg:                           Kc1=NO2N2O2NOg 1/2N2g+1/2O2g            Kc2=N21/2O21/2NO

Obviously, Kc2=1Kc1=14×104=12×102=50.0

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