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Q.

The equilibrium constant Kp  of reaction NH4HS(s)NH3(g)+H2S(g)  is expressed as x×10y . atm2. If the observed pressure of mixture in 20 atm what is ‘Y’?

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a

2

b

1

c

3

d

4

answer is B.

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Detailed Solution

NH4HS(s)NH3(g)+H2S(g)

t = 0

100 Moles of gases at equilibrium = 2x

t = eq

 1-x x x

XNH3=x2x=12 &PNH3=202=10atm

&     XH2S=x2x=12 &PH2S=202=10atm

KP=10×10=100=1.0×102atm2

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