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Q.

The equilibrium constant Kp for the reaction, 

2SO2(g)+O2(g)2SO3(g) at 1000 K is 3.5 atm-1
What would be the partial pressure of oxygen gas, if the equilibrium is found to have equal moles of SO2 and SO3?

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a

0.35 atm

b

2.85 atm

c

3.5 atm

d

0.285 atm

answer is D.

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Detailed Solution

In terms of partial pressure, the equilibrium constant is Kp for the reaction,

aA+bBcC+dD

Kρ=PCc×PDdPAa×PBb

Then for the given reaction,

2SO2(g)+O2(g)2SO3(g)Kp=3.5 atm-1

So,

Kp=PSO32PSO22PO2 [PSO3=PSO2]  3.5=1PO2PO2=0.285

So, option 4 is correct.

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The equilibrium constant Kp for the reaction, 2SO2(g)+O2(g)⇌2SO3(g) at 1000 K is 3.5 atm-1What would be the partial pressure of oxygen gas, if the equilibrium is found to have equal moles of SO2 and SO3?