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Q.

The equilibrium constants for the reactions

Zn(s)+Cu2+ (aq) Zn2++ (aq) Cu(s)Cu(s)+2Ag(aq)+Cu(aq)2++2Ag(s)

are K1 and K2 respectively then the equilibrium constant for the reaction

Zn(s)+2Ag(aq)+Zn(aq)+2+2Ag(s) will be.

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a

K1·K2

b

K1/K2

c

K1-K2

d

K1+K2

answer is B.

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Detailed Solution

 

Zn(s)+Cu2+ (aq) Zn2++ (aq) Cu(s)Cu(s)+2Ag(aq)+Cu(aq)2++2Ag(s)

 For reaction (1) and (2). We get,

2Zn+2Ag Zn2 + 2Ag

So, KeffK1.K2

Therefore, the correct answer is option (B) K1.K2.

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