Q.

The equilibrium constants for the stepwise formation of MCl, MCl2 and MCl3 are a, b and c respectively. If the equilibrium constant of formation of MCl3 is K, which of the following is correct?

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a

1/K=1/a+1/b+1/c

b

K=1/a×1/b×1/c

c

logK = loga+logb+logc

d

K= a+b+c

answer is C.

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Detailed Solution

: we have, (1) M+½ Cl2→MCl , K1=a

(2)MCl+1/2 Cl2→MCl2, K2=b

(3) MCl2+1/2 Cl2→MCl3, K3= c

(4) M+3/2Cl2→MCl3, K=not

So, K4= K1×K2×K3

Hence, logK= loga+logb+logc

Therefore, the correct answer is option (C) logK = loga+logb+logc.

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