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Q.

The equilibrium mixture for 2SO2(g)+O2(g)2SO3(g) present in 1litre vessel at 600°C contains 0.50, 0.12 and 5.0 mole of SO2,O2&SO3respectively.

a) Calculate KC for the given change at 600°C

b) Calculate KP

c) How many mole of O2 must be forced into the equilibrium vessel at 600°C in order to increase the concentration of SO3 to 5.2 mole?

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a

83.3 mol-1lit-1,11.62 atm-1 and 3.4 mole

b

833.33 mol-1lit-1,11.62 atm-1 & 3.4 mole

c

8.33 mol-1lit-1,1.162 atm-1& 0.68 mole

d

83.33 mol-1lit-1,1.162 atm-1& 0.17 mole

answer is B.

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Detailed Solution

a) K=5×50.22×0.12=833.33

b) KP=KC(RT)-1

=833.330.0821×873=11.62

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