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Q.

The equilibrium of the reaction N2(g)+3H2(g)2NH3(g)   is set up at 300 K by mixing  N2(g)  andH2(g).The standard free energy of formation of  NH3(g)  is -15.53 kJ/mol. If after one hour of mixing the partial pressure of  N2,H2  and  NH3, are 50, 2 and 200 bar respectively and the enthalpy change of reaction is -4.2 kJ, what is the entropy change of the reaction.  (in  JK1)[Given:ln100=4.6,  RT=2500  J]

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answer is 51.2.

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Detailed Solution

QP=(200)2(2)3×50=100   ΔG=ΔG+RTlnQ   =31.06+25001000×4.6 =19.56  ΔG=ΔHTΔS   19.56=4.2TΔS   15.36=TΔS ΔS=15.36300×100JK1   =51.2  JK1

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