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Q.

The equilibrium p-xyloquinone + methylene white p-xylohydroquinone + methylene blue may be studied conveniently by observing the difference in colour methylene white and methylene blue. One m mol of methylene blue was added to 1L of solution that was 0.24 M in 0.012M p-xylohydroquinone and 0.012 M in p-xyloquinone. It was then found that 4% of the added methylene blue was reduced to methylene white. What is the equilibrium constant of the above reaction? The equation is balanced with one mole each of 4 substances.

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answer is 480.

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Detailed Solution

A+BC+D12mmol 240mmol1mmol ~120.04 ~2400.96 K=240×0.9612×0.04=480

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