Q.

The equivalent conductance of 1N solution of an electrolyte is nearly

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a

102 times more than its specific conductance

b

103 times more than its specific conductance

c

Same as its specific conductance

d

10-3 times its specific conductance

answer is D.

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Detailed Solution

Explanation:

Equivalent conductance (Λₑ) is defined as the conductance of a solution containing one gram equivalent of an electrolyte. It is related to the specific conductance (κ) by the equation:

Λₑ = κ × (1000 / N)

Where:

Λₑ = Equivalent conductance (S·cm²·eq⁻¹)

κ = Specific conductance (S·cm⁻¹)

N = Normality of the solution (eq/L)

For a 1N (1 eq/L) solution, the equation simplifies to:

Λₑ = κ × 1000

Therefore, the equivalent conductance of a 1N solution is approximately 10³ times its specific conductance.

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