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Q.

The equivalent conductance of NaCl at concentration C and at infinite dilution are λC and λ respectively The correct relationship between λC and λ is given as (where, the constant B is positive)

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a

λC=λ(B)C

b

λC=λ+(B)C

c

λC=λ+(B)C

d

λC=λ(B)C

answer is C.

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Detailed Solution

According to Debye Huckel Onsager equation,
           λC=λBC
where, λC = limiting equivalent conductivity at concentration C
          λ  = limiting equivalent conductivity at infinite dilution
              C = concentration

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