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Q.

The equivalent conductance of M32 solution of a weak monobasic acid is 8.0 mho cm2.eq-1and at infinite dilution is 400 mho cm2.eq-1.The dissociation constant of this acid is 

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a

1.625×10-4

b

1.25×10-4

c

1.25×10-5

d

1.25×10-6

answer is A.

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Detailed Solution

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α=λvλ=8.0400=2×10-2; ka=2 =132×2×10-22 =1.25×10-5

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