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Q.

The equivalent weight of HCl in the given reaction K2Cr2O7 +14HCl  → 2KCl + 2CrCl3 + 3Cl2 + 7H2O is

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a

36.5

b

85.1

c

73

d

16.25

answer is D.

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Detailed Solution

K2Cr2O7+14H+1Cl-12kCl-1+2CrCl-13+3Cl20+7H2O

Total charge of 'Cl' on LHS = -14
Total charge of 'Cl' on RHS = -8
Increases in Oxidation number/14mole of HCl = 6
MW of HCl = 36.5

EHCl=14(36.5)6=85.1

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The equivalent weight of HCl in the given reaction K2Cr2O7 +14HCl  → 2KCl + 2CrCl3 + 3Cl2 + 7H2O is