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Q.

The equivalent weight of HCl in the given reaction K2Cr2O7 + 14HCl  2KCl + 2CrCl3 + 3Cl2 + 7H2O is

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a

73

b

36.5

c

16.25

d

85.1

answer is D.

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Detailed Solution

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K2Cr2O7+14H+1Cl-12kCl-1+2CrCl-13+3Cl20+7H2O

n-factor represents the number of H+ ions an acid can give or the number of OHions a base can produce.
n-factor = 614
As we know,

The molecular mass of HCl =36.5 gm /mole
Equivalent weight =molecular massn- factor
By putting the values in the above formula, we get
Equivalent weight = 36.5×146
Equivalent weight = 85.1

Hence, the equivalent weight of HCl in the given reaction is 85.1.

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