Q.

The equivalent weight of KMnO4  in acidic medium is

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a

52.66

b

158

c

39.6

d

31.6

answer is A.

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Detailed Solution

The balanced chemical equation for the oxidation of KMnO4 in acidic medium is given below. 

2KMnO4+3H2SO4K2SO4+3H2O+2MnSO4+5(O)

In the above equation, the net change is as given below.

Mn+7+5e-Mn+2

Equivalent weight of  KMnO4=molecular weight of KMnO4No of electrons transfered

Note: Molecular weight of KMnO4 is 158g/mol.

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