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Q.

The exact volume of 1 M NaOH solution required to neutralize 50 mL of 1M H3PO3 solution and 100 mL of  2M H3PO2  respectively are

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a

100 mL,  200 mL

b

100 mL, 100 mL

c

100 mL,  50 mL 

d

50 mL,   50 mL

answer is C.

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Detailed Solution

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2NaOH+H3PO3Na2HPO3+2H2O

Mb=1M     Ma=1MVb=x           Va=50mLnb=2            na=1                            MaVana=MbVbnb    1×501=1×x2

x = 100 mL

NaOH+H3PO2NaH2PO2+H2O

Mb=1M     Ma=2MVb=x           Va=100nb=1            na=1                    μaVana=μbVbnb    2×1001=1×x1

x=Vb=200 mL

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