Q.

The expression to compute pH of sodium acetate solution is

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a

pH=12pKw+12pKaCH3COOH+12log([salt]/M)

b

pH=12pKw+12pKaCH3COOH12log([salt]/M)

c

pH=12pKaCH3COOH12pKw+12log([ salt ]/M)

d

pH=12pKw12pKaCH3COOH12log([salt]/M)

answer is C.

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Detailed Solution

Ac+H2OHAc+OHKh=KwKa=[HAc]HOAcOH2Ac0 OH2=KwKbAc0; KwH+22=KwKaAc0

which on taking log and multiplying by- 1 gives pH=12pKw+12pKa+12log([salt]/M)

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