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Q.

The extraction of which of the following metals involves complex formation? 

a) Au    b) Cu    c) Ag
 

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a

Both b and c

b

a only 

c

Both a and b

d

Both a and c

answer is D.

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Detailed Solution

Cyanide process :- Their process used for Au, Ag by (Mac-Arthur forrest cyanide
process).

Silver and gold are extracted by a method involving complex formation.
Powdered argentite is reacted with a dilute solution of sodium cyanide in the presence of air. The silver from the ore is dissolved in the cyanide solution forming sodium argentocyanide.

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Now metallic zinc is added to the complex salt solution which being more electropositive element than silver, displaces it from the solution.

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