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Q.

The factor of  ΔG values are important in metallurgy. The ΔG values for the following reactions at 800°C are given as

S2(s)+2O2(g)2SO2(g),ΔG=544kJ

2Zn(s)+S2(s)2ZnS(s),ΔG=293kJ

2Zn(s)+O2(g)2ZnO(s),ΔG=480kJ

The  ΔG for the reaction, 

2ZnS(s)+3O2(g)2ZnO(s)+2SO2(g) Will be 

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a

-229Kj

b

-357 kJ

c

 -773kJ

d

-731kJ

answer is B.

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Detailed Solution

ΔG  of formation of different substance are as

 2SO2=544kJ 2Zns=293kJ 2ZnO=480kJ

For the reaction,

2ZnS+3O2(g)2ZnO(s)+2SO2(g)

ΔG=[ΔG(products)ΔG(reactants)]

=[(480)+(544)(293)]

=1024+293=731kJ

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