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Q.

The factor of   values are important in metallurgy. The G values for the following reactions at 800°C are given as
 S2(s)+2O2(g)2SO2(g),ΔG=544kj2Zn(s)+S2(s)2ZnS(s),ΔG=293kj2Zn(s)+O2(g)2ZnO(s),ΔG=480kj
The G  for the reaction, 
2ZnS(s)+3O2(g)2ZnO(s)+2SO2(g)
will be 

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a

-357 kJ

b

-731kJ

c

-673kJ

d

-229KJ

answer is B.

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Detailed Solution

G of formation of different substance are as
 2SO2 = -544 kJ
 2Zns = -293 kJ
 2ZnO = -480 kJ
For the reaction,
2ZnS+3O2(g)2ZnO(s)+2SO2(g)ΔG=ΔG(products )ΔG(reactan ts )=[(480)+(544)(293)]=1024+293=731kJ

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