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The false statements among the following are

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A primary carbocation is less stable than a tertiary carbocation

A secondary propyl carbocation is less stable than allyl carbocation

A tertiary free radical is more stable than a primary free radical

Isopropyl carbonion is more stable than ethyl carbanion

answer is B, D.

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Detailed Solution

Statements (b) and (d) are wrong since 2º propyl carbocation is little more stable than allyl carbocation and ethyl carbanion is more stable than isopropyl carbanion.

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