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Q.

The figure below shows the plot of PV/nT versus P for oxygen gas at two different temperatures    

Read the following statements concerning the curves given below   

Question Image

i)    The dotted line corresponds to the 'ideal' gas behaviour    
ii)     T1 > T2    
iii)     The value of PV/nT at the point, where the curves meet on the y-axis is the same for all gases Which of the above statement is true?

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a

i only   

b

all of these

c

i and ii   

d

none of these

answer is C.

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Detailed Solution

PV = nRT

\therefore \frac{{PV}}{{nT}} = R

For ideal gas, R is constant which is represented by dotted line.

At high temperature and low pressure, a real gas behaves like an ideal gas. So as temperature T increases and pressure decreases the graph of PV/T versus P approaches the dotted line. Hence T1 > T2.

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