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Q.

The final product formed when acetylene gas is passed through dilute sulphuric acid in presence of heavy metal cation at 60-65°Cis

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a

Vinyl alcohol

b

Ethanal

c

Ethenol

d

Ethanol

answer is D.

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Detailed Solution

When acetylene gas is passed through dilute sulphuric acid at 60 -65 °C in presence of mercuric sulphate as catalyst, a water molecule adds up and finally acetaldehyde is formed. This is called hydration. Vinyl alcohol and acetaldehyde are tautomers.

CHCH+HOH60°C,1%H2SO430-40%H2SO4CH2=CHOHethenol+CH3-CHO

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