Q.

The first and second dissociation constants of an acid H2A and 1.0×105 and 5.0×1010 respectively. The overall dissociation constant of the acid will be:

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a

5.0×105

b

5.0×1015

c

0.2×105

d

5.0×1015

answer is A.

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Detailed Solution

koverall =k1×k2

The overall dissociation constant is equal to the product of first and second dissociation constant. It is Ka=Ka1×Ka2=1.0×105×5.0×1010=5.0×1015

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