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Q.

The first ionization enthalpies of Na, Mg and Si are respectively 496, 737 and 786 kJ mol-1. What would be the first ionization enthalpy of Al in kJ mol-1 ?

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a

575

b

450

c

800

d

750

answer is C.

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Detailed Solution

The atomic number of Al is 13 and its electronic configuration of Al is 1s2 2s2 2p6 3s2 3p1. The first Ionization enthalpy of Al is less than Mg because Mg has a filled stable configuration but less than Na (as Na is a highly positive metal). So, the value of Al is less than Mg but greater than Na. So, the first ionization energy of Al is around 575 kJ/mol.

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