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Q.

The first IP of lithium is 5.41eV and electron affinity of Cl is -3.61eV. Calculate ΔH in KJmol–1 for the reaction
Li(g) + Cl(g) → Li(g)+ + Cl(g)

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a

173.7

b

1737

c

17.3

d

1.73

answer is A.

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Detailed Solution

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Li(g) + Cl(g)  Li+(g) + Cl(g) ; H=IP+EA H=5.41-3.61=1.8ev.=1.8×1.602×10-19×6.023×1023       =173.67KJ

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