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Q.

The first ( ΔrH1) and the second (ΔrH2 ) ionization enthalpies (in kJ mol1 ) and the  (ΔegH ) electron gain enthalpy (in kJ  mol1) of a few elements are given below: 

ElementsΔrH1ΔrH2ΔegH
l5207300-60
II4193051-48
III16813374-328
IV10081846-295
V23725251+48
VI7381451-40

Choose the correct option(s):

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a

The most reactive metal is II.

b

III and IV are both non-metals, III being the most reactive non-metal.

c

VI is a metal, and it can form a stable binary halide of the formula MX  (X=halogen).

d

V is the most unreactive element.

answer is A, B, D.

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Detailed Solution

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I, II, and VI must be metals as they have low  ΔrH1.
III and IV must be non-metals as they have large negative ΔegH .
V must be a noble gas as it has high IEs as well as +ve  ΔegH.
VI may be a 2nd group metal as ΔrH1 relatively small and ΔrH2  is just about double.

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