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The fixation of $N_{2}$ by certain bacteria is a biological reduction reaction of great interest. Very few nonbiochemical systems are known which will react with $N_{2}$ at room temperature and atmospheric pressure one such compound is the titanium (II) compound titanocene, ${(C_{5} H_{5})}_{2} T i$ sometimes also abbreviated as $C p_{2} T i$ , a sandwich compound like ferrocene. Select the correct statement(s) about titanocene (I) and its dinitrogen complex [Bond length of free $N_{2} 109.8$ pm]
Note: Consider $N_{2}$ as Pi acceptor.

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The IUPAC name for the complex (II) would be bis(cyclopentadienyl) bis (dinitrogen) titanate (II)

NN bond lengths in the complex will be higher than 109.8 pm

The NN bond length in the complex is less than 109.8 pm

Of the two complexes, only complex (II) follows Sidgwick EAN rule

answer is B, D.

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Detailed Solution

bis (cyclopentadienyl) bis (dinitrogen) titanium (II)
De to back bonding, electrons enters into ABMO of $N_{2}$ so bond length N-N bond increases

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