Q.

The following are some statements about oxides
of VA group elements
I) N2O molecule is linear
II) NO2 molecule is angular
III) N2O5 molecule is angular
The correct combination is

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a

II & III are correct only

b

All are correct

c

I & II are correct only

d

I & III are correct only

answer is D.

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Detailed Solution

N2O is a polar molecule that has a linear shape.

There are lone pairs on both O and N atoms in NO2. As a result, the oxygen atoms are spread widely and the angle that is formed is nearly134o. This implies that NO2 molecular geometry will be bent.

Solid N2O5 is a salt, consisting of separated anions and cations. The cation is the linear nitronium ion, NO2+ and the anion is the planar nitrate ion, NO3-.

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