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Q.

The following are some statements regarding dissociation of lime stone according to the equation 

CaCO3(s)CaO(s)+CO2(g);ΔH=110k.J.

the reaction is carried in a closed vessel.

A) The pressure of CO2 increases when temperature is increased.

B) The pressure of CO2 increases when temperature is decreased.

C) The pressure of CO2 remains same when volume of vessel is halved.

The incorrect statements are

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a

A and B

b

B and C

c

A and C

d

All A, B, C

answer is B.

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Detailed Solution

According to Le-Chatelier's principle, addition of gaseous reactants (or) removal gaseous products favours forward reaction.The decomposition of CaCO3 is endothermic it is favoured at high temperature.

If temperature increases more amount of CO2 is formed. Thus  PCO2 increases.

Hence A) is true     B) is false

When volume of vessel is halved then  pressure of CO2 changes. B, C are incorrect.

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