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Q.

The following are some statements related to IIA group metals.

I) The reaction with water increases from Be to Ba

II) The ionic nature of hydrides decreases from Be to Ba

III) The thermal stability of the peroxides increases with increase in cationic size
IV) BeF2 is soluble in water
The correct statements are of
 

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a

 I and III
 

b

II and IV
 

c

I, II and III
 

d

I, III and IV

answer is D.

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Detailed Solution

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As electropositivity of Metal increases reaction with water increases, 

MIIA+2H2OMOH2+H2

BeH2<MgH2<CaH2<SrH2<BaH2

As the size of central metal increases electropositivity (or) metallic nature increases and hence ionic nature of hydride increases 
BeH2 & MgH2's are covalent hydrides 
Ca,Sr,BaH2 are ionic hydrides

As the size of cation increases stability of peroxides increases
Since, a large size cation [Ba+2] will stabilise the larger size anion [O2-2]

Fluorides of alkaline earth metals except BeF2 are insoluble in water. The solubility of BeF2 in water is due to the higher hydration energy on account of the smaller size of Be2+ ion and F ion and the high charge density of Be2+ ion.

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