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Q.

The following are some statements related to VA group hydrides.

I.    Reducing property increases from NH3 to BiH3

II.   Tendency to donate lone pair decreases from NH3 to BiH3

III.  Thermal stability of hydrides  decreases from NH3 to BiH3

IV.   Bond angle of hydrides decreases from NH3 to BiH3

The correct statements are

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a

I and IV

b

 I, II, III and IV

c

I, III and IV

d

I, II and IV    

answer is A.

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Detailed Solution

Reducing property 1thermal stability

Tendency to donate lone pair  Lewis basic nature 

Thermal stability 1M-H bond length 

Bond angle 1size of central atom(for same type of compounds of same group with similar type of electronic repulsions)

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