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Q.

The following are some statements related to VA group hydrides 

I : Reducing property increases from NH3 to BiH3 

II : Tendency to donate lone pair decreases from NH3 to BiH3 

III : Ease of replacing H with Cl decreases from NH3 to BiH3 

IV :  Ease of formation of hydrides decreases from NH3 to BiH3 

The correct statements are : 

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a

 I, II, III, IV

b

I, III and IV

c

I, II and IV

d

I and IV 

answer is A.

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Detailed Solution

(I) The reducing property of the hydrides of VA group increases from NH3​ to BiH3​ as MH bond length increases.
(Where, M=N, P As, Sb,Bi )
NH3​<PH3​<AsH3​<SbH3​<BiH3​
(II) The tendency to donate lone pair or basic strength decreases from NH3​ to BiH3​.
NH3​>PH3​>AsH3​>SbH3​>BiH3​
(III) Thermal stability of VA group hydrides decreases from NH3​ to BiH3​.
NH3​>PH3​>AsH3​>SbH3​>BiH3​
(IV) Bond angle of VA group hydrides decreases from NH3​ to BiH3​
NH3​>PH3​>AsH3​>SbH3​>BiH3


 

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