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Q.

The following are statements regarding sodium carbonate
i) The chemical formula of washing soda is Na2CO3.10H2O
ii) Aqueous solution of sodium carbonate is acidic in nature
iii) The prinicple involved in the preparation of Na2CO3 by Solvay process is very low solubility of NaHCO3.

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a

i and iii are correct

b

i and ii are correct

c

ii and iii are correct

d

all are correct

answer is A.

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Detailed Solution

Washing sida Na2CO3 . 10H2O [Decahydrate of sodium carbonate]
Na2CO3 → 2Na+ + CO3-2
Na2CO3 salt undergoes anionic hydrolysis
 

large CO_3^{ - 2}; + ;2{H_2}O; to ;{H_2}C{O_3}; + ;2Omathop Hlimits^ circleddash


 

large therefore

The aqueous solution of Na2CO3 is alkaline (or) basic in nature
Hint: Ions of weak acid & base only undergoes hydrolysis
→ Na2CO3 is prepared by solvay process
NH3 + CO2 + H2O → NH4HCO3
NH4HCO3 + NaCl → NH4Cl + NaHCO3
 

Question Image

 


 

→ Due to the low solubility of NaHCO3 , it gets precipitated in the reaction of NaCl with NH4HCO3

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