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Q.

The following are the statements regarding polarizing power of IIA group cations 

i) Be always forms covalent compounds due to high polarizing power of Be2+ ions 

ii) Be always form covalent compounds due to low polarizing power of Be2+ions 

iii) Polarizing power of IIA cations decreases from Be2+ ion to Ba2+ ion 

The correct combination is 

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a

ii and iii are correct 

b

i, ii, iii are correct

c

iii and i are correct 

d

i and ii are correct

answer is C.

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Detailed Solution

  • Beryllium is an IIA group element having small size. And the polarizing power of Be is high due to its small size hence is more covalent in nature. Covalent compounds are formed due to high polarizing power of Be not low.

And we know, larger the size of cation, lower is the polarizing power. As, the size of Be+2<Ba+2 hence, the polarizing power decreases from Be+2 to Ba+2. So, the option i and iii are correct.

Therefore, option (C) is correct.

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