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Q.

The following mechanism has been proposed for the reaction of NO with Br2 to form NOBr

NO(g)+Br2(g)NOBr2(g)

NOBr2(g)+NO(g)2NOBr(g)

If the second step is rate determining step, then the Order of reaction with respect to NO(g) is

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a

2

b

1

c

0

d

3

answer is C.

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Detailed Solution

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Since second step is slow , hence

rate =K[NOBr2]1[NO]1(1)

From equation (1) K1=[NOBr2][NO]1[Br2]1

NOBr2=K1NO1Br21(2)

Sub. (2) in (1) , we get

rate=KK1NOBr2NO

rate=KNO2Br21

Rate w.r.to ‘NO’ is 2

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