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Q.

The following mechanism has been proposed for the exothermic catalysed complex reaction: 

A+BfastslowIABk1AB+Ik2P+A

If k1 is much smaller than k2, the most suitable qualitative plot of potential energy (P.E.) versus reaction co-ordinate (R.C.) for the above reaction.

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a

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b

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c

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d

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answer is B.

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Detailed Solution

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A+BfastslowIAB; so Ea(f) is high and Ea(b) is low. 

k1<<k2; so Ea for this step is very high and next step is low and overall reaction is exothermic. 

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