Q.

The following reaction was carried out in H2O

   Cl2+2I-I2+2Cl-

The initial concentration of I- was 0.25 mol L- and concentration after 10 min. is 0.23mol L-.Calculate rate of disappearance of I- and appearance of I2.

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answer is 0.001.

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Detailed Solution

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I-=I-final-I-initial            =0.23-0.25 mol L-1=-0.02 mol L-1

t=Tfinal-Tinitial=10 min-0 min=10 min

Rate of disappearance of I- is:

12ΔIΔt=120.02 mol L-110 min=0.001 mol L-1min-1

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