Q.

The formation of oxide ion O2g, from oxygen atom requires first an exothermic and then an endothermic step as shown below

O(g)+eO(g);ΔH=141kJmol1O(g)+eO2(g);ΔH=+780kmol1

Thus, process of formation of O2 in gas phase is unfavourable even though O2 is isoelectronic with neon. It is due to the fact that

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a

addition of electron in oxygen results in larger size of the ion

b

O¯ ion has comparatively smaller size than oxygen atom

c

electron repulsion outweighs the stability gained by achieving noble gas configuration

d

oxygen is more electronegative

answer is C.

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Detailed Solution

Although O2 has noble gas configuration and isoelectronic with neon but its formation is unfavourable due to the strong electronic repulsion between the negatively charged O¯  ion and the second electron being added.
Hence, the electron repulsion outweighs the stability gained by achieving noble gas configuration.

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